Looking every inch the villain, Chrishell's special effects makeup game was nothing short of on point.
The reality TV star opted for a plunging version of Angelina's costume for the character, as Chrishell showed off her ample assets in a plunging neckline.
She then teamed her evil look up with gladiator-style black heeled boots, as well as fishnet stockings for an extra daring element.
Chrishell's pro dance partner Gleb Savchenko also stunned in an outfit to match, opting for a black and purple outfit to not steal focus from the newly-single beauty.
Later that evening, the pair danced to In the Air Tonight by VonLichten.
Her Dancing With The Stars stint comes after she recently split from husband Justin Hartley.
The This Is Us star is said to have broken the news to his wife that he was divorcing her by text message, which he has never commented on.
Everything seemed to be fine between Chrishell and Justin until November last year when he filed for divorce.
She told co-star Amanza Smith: “He text me that we were filed. Forty-five minutes later, the world knew."
She added: “I talked to him right after because I thought that must be a joke. But that was kind of the end of the communication.”
Meanwhile Justin recently appeared on The Ellen Show, as he insisted he's "really happy" with where he is in his life at the moment.
He said: "I'm happy with my career. I'm happy with my personal life…I'm healthy, I'm safe. I'm, I mean, all of those things. So, I'm very thankful…I will have a public life, but I will be very private about my personal affairs."
The actor said the couple had actually split in July - despite them being pictured together at several red carpet events between then and the end of their marriage.
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